- Interactions between carboranethiols and metal (Au/Ag/Cu) surfaces.
- Boron hydride clusters as building blocks for 2-D and 3-D molecular assemblies.
- Au single crystals and various other dimensional levels of gold
Publications
] . Preparation and structures of 1 '-(diphenylphosphino)ferrocenecarboxaldehyde and {1 '-(diphenylphosphino)ferrocenyl}methanol. Inorganic Chemistry Communications. 2001;4(11). Available at: http://www.sciencedirect.com/science/article/pii/S1387700301002982.
. Acid-catalyzed self-alkylation of FcCH(2)NHPh. Solid-state structures of FcCH(2)NHPh and (FcCH(2))2NPh. Inorganic Chemistry Communications. 2002;5(1). Available at: http://www.sciencedirect.com/science/article/pii/S138770030100346X.
Synthesis and catalytic activity of spaced ferrocene oxazolines. Collection of Czechoslovak Chemical Communications. 2003;68(7). Available at: http://cccc.uochb.cas.cz/68/7/1206/.
Carborane Thiol-modified Gold Surfaces. A Study and Comparison of Modified Cluster and Flat Surfaces. 12th International Meeting on Boron Chemistry (IMEBORON-XII). 2005.
imeboron_xii_2005_t_base_talk.pdf (2.19 MB) imeboron_xii_2005_t_base_abstract.pdf (184.38 KB)
imeboron_xii_2005_t_base_talk.pdf (2.19 MB) imeboron_xii_2005_t_base_abstract.pdf (184.38 KB) Carboranethiol-Modified Gold Surfaces. A Study and Comparison of Modified Cluster and Flat Surfaces. Langmuir. 2005;21(17). Available at: http://pubs.acs.org/doi/abs/10.1021/la051122d.
. Carboranethiol-modified surfaces of gold colloids and films. Faculty of Chemical Technology, Institute of Inorganic Chemistry. 2007;Ph.D.:60. 2007_tomasbase_phdthesis.pdf (1.91 MB)
2007_tomasbase_phdthesis.pdf (1.91 MB). The adhesion and growth of vascular smooth muscle cells in cultures on carboranethiol-modified gold films. Engineering of Biomaterials. 2008;11. Available at: http://neutron.ujf.cas.cz/vdg/LC06041/2008_W_Parizek_1.pdf.
. Chemie podivnych tvaru aneb Vylet do rise hydridu boru (in Czech). Vesmir. 2008;87:748-749. Available at: http://casopis.vesmir.cz/clanky/clanek/id/8022. base_londesborough_vesmir_2008-11_vol87_pp748-749.pdf (175.89 KB)
base_londesborough_vesmir_2008-11_vol87_pp748-749.pdf (175.89 KB). A comparison of boron hydride- and hydrocarbon-based thiol derivatives assembled on gold surfaces. NSTI Nanotechnology Conference and Trade Show. 2008;1. Available at: http://www.nsti.org/procs/Nanotech2008v1/2/T35.902.
Gold Micrometer Crystals Modified with Carboranethiol Derivatives. J. Phys. Chem. C. 2008;112(37). Available at: http://pubs.acs.org/doi/abs/10.1021/jp802281s.
Carborane-thiol-silver interactions. A comparative study of the molecular protection of silver surfaces. Surface and Coatings Technology. 2010;204. Available at: http://www.sciencedirect.com/science/article/pii/S0257897210001106.
An Experimental Solution to the "Missing Hydrogens" Question Surrounding the Macropolyhedral 19-Vertex Boron Hydride Monoanion [B19H22](-), a Simplification of Its Synthesis, and Its Use As an Intermediate in the First Example of syn-B18H22 to anti-B18H22. Inorganic Chemistry. 2010;49(9):4092–4098. Available at: http://pubs.acs.org/doi/abs/10.1021/ic901976y.
Reversible Capture of Small Molecules On Bimetallaborane Clusters: Synthesis, Structural Characterization, and Photophysical Aspects. Inorganic Chemistry. 2011;50. Available at: http://pubs.acs.org/doi/abs/10.1021%2Fic200374k.
. Self-assembled monolayers of polyhedral dicarbadodecaborane dithiols: a computational assesment of high coverage patterns. 18th Interdisciplinary Surface Science Conference (ISSC-18). 2011. Available at: http://www.iop.org/conferences. issc18_2011_j_machacek_poster.pdf (6.02 MB)
issc18_2011_j_machacek_poster.pdf (6.02 MB) Tuning the surface potential of Ag surfaces by chemisorption of oppositely-oriented thiolated carborane dipoles. Journal of Colloid and Interface Science. 2011;354. Available at: http://www.sciencedirect.com/science/article/pii/S0021979710012385.
. Carbon-substituted 9,12-dimercapto-1,2-dicarba-closo-dodecaboranes via a 9,12-bis(methoxy-methylthio)-1,2-dicarba-closo-dodecaborane precursor. Polyhedron. 2012;45. Available at: http://www.sciencedirect.com/science/article/pii/S0277538712005207.
Carboranedithiols: Building Blocks for Self-Assembled Monolayers on Copper Surfaces. Langmuir. 2012;28. Available at: http://pubs.acs.org/doi/abs/10.1021%2Fla302334x.
. Carboranethiols: Building Blocks for Self-Assembled Monolayers on Copper Surfaces, or a Novel Class of Etchants?. European Materials Research Society, Spring Meeting. 2012. e-mrs_springmeeting_2012_t_base_poster.pdf (646.88 KB) e-mrs_springeeting_2012_t_base_abstract.pdf (16.55 KB)
e-mrs_springmeeting_2012_t_base_poster.pdf (646.88 KB) e-mrs_springeeting_2012_t_base_abstract.pdf (16.55 KB) Decaborane Thiols as Building Blocks for Self-Assembled Monolayers on Metal Surfaces. Inorganic Chemistry. 2012;51.
Nucleated Crystallization of Isotactic Polypropylene in Multilayered Sandwich Nanocomposites with Gold Particles. Journal of Applied Polymer Science. 2012;125. Available at: http://onlinelibrary.wiley.com/doi/10.1002/app.36589/abstract.
. The gaseous structure of closo-9,12-(SH)2-1,2-C2B10H10, a modifier of gold surfaces, as determined using electron diffraction and computational methods. Dalton Transactions. 2013;42. Available at: http://pubs.rsc.org/en/results?artrefjournalname=dalton%20trans.&artrefstartpage=12015&artrefvolumeyear=2013&fcategory=journal.
Self-Assembled p-Carborane Analog of p-Mercaptobenzoic Acid on Au{111}. Chemistry of Materials. 2015;27(15):5425–5435. Available at: http://pubs.acs.org/doi/pdf/10.1021/acs.chemmater.5b02263.
Thermal isomerizations of monothiolated carboranes (HS)C2B10H11 and the solid-state investigation of 9-(HS)-1,2-C2B10H11 and 9-(HS)-1,7-C2B10H11. Journal of Organometallic Chemistry. 2015;798(1):132-140. Available at: http://www.sciencedirect.com/science/article/pii/S0022328X15300462.
10-vertex closo-carborane: a unique ligand platform for porous coordination polymers. CrystEngComm. 2016;18(12):2036-2040. Available at: http://pubs.rsc.org/en/content/articlelanding/2016/ce/c5ce02501j#!divAbstract.
